Pemanfaatan Fly Ash sebagai Adsorben dalam Pemurnian Crude Glycerol dari Hasil Produk Samping Biodiesel
Abstract
The increase of biodiesel production capacity is followed by an increase in crude glycerol production as a by-product. Crude glycerol still has a low purity and a lot of impurities so it requires special treatment so that it can be utilized and valuable. One of the ways to increase the purity of crude glycerol is in the adsorption process. This study aims to determine the best conditions for the adsorption process and the characteristics of the glycerol produced after the adsorption process. The initial condition of crude glycerol purity is low, namely 67.8%, so purification is needed. One way of purifying crude glycerol is by physically separating it using fly ash as an adsorbent. The experiment was carried out with the adsorption process using fly ash with the adsorbent mass variable 30,35,40,45, and 50 grams and the adsorption time variable was 50,60, and 70 minutes. The purified products are analyzed quantitatively and qualitatively, including glycerol content, density, viscosity, moisture content, ash, and MONG. The best conditions for the adsorption process using fly ash were obtained at a mass of 50 grams with a time of 50 minutes with the results that the glycerol content was 97.5%, water content 0.03%, ash content 0.0432%, MONG content 2.426%, density 1.253 gr / ml , viscosity 233.56 cP. Based on these results, purified glycerol was obtained that met the quality standards of SNI 06-1564-1995.
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N. F. Nasir, M. F. Mirus, and M. Ismail, “Purification of crude glycerol from transesterification reaction of palm oil using direct method and multistep method,” in IOP Conference Series: Materials Science and Engineering, 2017. doi: 10.1088/1757-899X/243/1/012015.
M. R. Monteiro, C. L. Kugelmeier, R. S. Pinheiro, M. O. Batalha, and A. da Silva César, “Glycerol from biodiesel production: Technological paths for sustainability,” Renewable and Sustainable Energy Reviews. 2018. doi: 10.1016/j.rser.2018.02.019.
S. Hu, X. Luo, C. Wan, and Y. Li, “Characterization of crude glycerol from biodiesel plants,” Journal of Agricultural and Food Chemistry, vol. 60, no. 23, pp. 5915–5921, 2012, doi: 10.1021/jf3008629.
T. Attarbachi, M. D. Kingsley, and V. Spallina, “New trends on crude glycerol purification: A review,” Fuel, vol. 340, p. 127485, May 2023, doi: 10.1016/j.fuel.2023.127485.
N. Suseno, T. Adiarto, R. Alviany, and K. Novitasari, “PEMURNIAN GLISEROL HASIL PRODUK SAMPING BIODIESEL DENGAN KOMBINASI PROSES ADSORPSI-MIKROFILTRASIEVAPORASI,” Jurnal Teknik Kimia, 2019, doi: 10.33005/tekkimv13i2.1406.
R. S. Ningsih, “Pemanfaatan Limbah Coal Fly Ash (Abu Layang Batubara) Sebagai Adsorben dalam Pemurnian Crude Glycerol (Gliserol Kasar),” Universitas Sumatera Utara, 2019.
Q. (Sophia) He, J. McNutt, and J. Yang, “Utilization of the residual glycerol from biodiesel production for renewable energy generation,” Renewable and Sustainable Energy Reviews. 2017. doi: 10.1016/j.rser.2016.12.110.
M. Hunsom and C. Autthanit, “Preparation of sludge-derived KOH-activated carbon for crude glycerol purification,” Journal of Material Cycles and Waste Management, 2017, doi: 10.1007/s10163-015-0402-y.
G. Xu and X. Shi, “Characteristics and applications of fly ash as a sustainable construction material: A state-of-the-art review,” Resources, Conservation and Recycling. 2018. doi: 10.1016/j.resconrec.2018.04.010.
R. Arora, “Adsorption of heavy metals-a review,” in Materials Today: Proceedings, 2019. doi: 10.1016/j.matpr.2019.07.462.
F. C. Suci, “Pemanfaatan abu layang batubara (Fly Ash) Teraktivasi sebagai Adsorben Ion Logam Pb (II),” Universitas Airlangga, 2012.
J. R. B. Witono, M. Angela, Y. Agnes, and C. Carissa, “Sistem Integrasi Koagulasi dan Adsorpsi dalam Reduksi Logam Berat (Cr6+ dan Cu2+) pada Limbah Cair Industri Tekstil,” no. 1693–4393, pp. 1–7, 2015.
T. Hemalatha and A. Ramaswamy, “A review on fly ash characteristics – Towards promoting high volume utilization in developing sustainable concrete,” Journal of Cleaner Production. 2017. doi: 10.1016/j.jclepro.2017.01.114.
I. Aziz, R. C. Sulistina, Hendrawati, and L. Adhani, “Purification of Crude Glycerol from Acidification Using Tea Waste,” IOP Conference Series: Earth and Environmental Science, vol. 175, p. 012010, Jul. 2018, doi: 10.1088/1755-1315/175/1/012010.
M. Hunsom and C. Autthanit, “Adsorptive purification of crude glycerol by sewage sludge-derived activated carbon prepared by chemical activation with H3PO4, K2CO3 and KOH,” Chemical Engineering Journal, 2013, doi: 10.1016/j.cej.2013.05.120.
M. S. H. S. Hasmalina Nasution, “PENENTUAN WAKTU KONTAK DAN pH OPTIMUM PENYERAPAN ZAT WARNA DIRECT YELLOW MENGGUNAKAN ABU TERBANG (FLY ASH) BATUBARA,” Semirata 2015, 2016.
DOI: https://doi.org/10.32672/jse.v8i2.5981
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